Dean and Sam are fighting on opposite sides
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Summary
Sam can't be a true supervillain if he doesn't have any powers. Right?
-or-
The Devil is a feared villain that plagues the country. You'd think a villain who livestreams online every other week would be easy to catch, but no. The hero organization "Angels" has never been able to catch him. When he posts an advertisement online, looking for an apprentice, the Angels are disturbed.
Sam Winchester, the brother of an Angel, never had any powers, and he hates himself for it. Wanting to be somebody, he responds to that advertisement... and he's the one The Devil accepts.